Payne has scored two goals in four appearances in the league for Sevilla.
Also in action was Rasheedat Ajibade who was later taken off in the 79th minute.
Payne scored with 10 minutes into the second half to make it 1-1.
It is the 28-year-olds second goal in her last three games.
Sevilla have recorded just one win (three defeats) in their four league games this season.
They occupy 10th place while Atletico Madrid are second behind Real Madrid.
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