Super Eagles forward Victor Osimhen was in action for Napoli in the game.
Vinicius Jr, Jude Bellingham and Federico Valverde were all on target for Real Madrid.
Napoli got their goals through Leo Ostigard and Piotr Zielinski.
At the Old Trafford, Manchester United lost 3-2 against Galatasaray.
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Rasmus Hojlund scored a brace for the Red Devils.
Wilfred Zaha netted against his old club with Muhammed Akturkoglu and Mauro Icardi also finding target.
Manchester United finished the game with 10-men following Casemiros dismissal.
Lens rallied to beat Arsenal 2-1 at the Stade Bollaert-Delelis in another fixture.
Gabriel Jesus gave Arsenal the lead on 14 minutes but Lens won the game through Adrien Thomasson and Elye Wahi strikes.
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